1997 BSc(Hons), Australian National University 2002 PhD, Australian National University 2002 Postdoctoral Research, University of NSW 2003-5 Alexander von Humboldt Research Fellow, Max Planck Institute for Polymer Research, Mainz 2005-8 ARC Postdoctoral Fellow, University of Sydney 2008-12 Lecturer, University of Otago 2009-18 MacDiarmid Institute for Advanced Materials and Nanotechnology, Associate Investigator 2012-18 Senior Lecturer, University of Otago 2018- Associate Professor, University of Otago 2018-MacDiarmid Institute for Advanced Materials and Nanotechnology, Principal Investigator 2020-22 Associate Dean (Postgraduate), Division of Sciences 2023- Head of Department
Research
Our research centres on the design, synthesis and characterisation of new carbon-rich molecular materials, in particular, those based on polyaromatic building blocks and often incorporating metals. While much of our experimental work is focused on the synthesis of molecules, we are also interested in the how these molecules interact with each other through intermolecular interactions in solution, in the bulk (solid, liquid crystalline mesophases) and on surfaces. This knowledge enables us to design new molecules that have not only the desired physical properties (e.g. optical, electronic), but also the ability to self-organise from solution into ordered nanoscale structures.
Main Research Interests:
synthesis and properties of carbon-rich molecular materials
supramolecular chemistry and self-assembly
organometallic chemistry and catalysis
materials for hydrogen storage
metal-containing liquid crystals
crystallography
Publications
Smith, J. N., Ennis, C., & Lucas, N. T. (2021). Rigid, biconical hydrogen-bonded dimers that strongly encapsulate cationic guests in solution and the solid state. Chemical Science, 12, 11858-11863. doi: 10.1039/d1sc01802g
Journal - Research Article
Smith, J. N., Brind, T. K., Petrie, S. B., Grant, M. S., & Lucas, N. T. (2020). One-step synthesis of C2v-symmetric resorcin[4]arene tetraethers. Journal of Organic Chemistry, 85, 4574-4580. doi: 10.1021/acs.joc.0c00128
Journal - Research Article
Swaney, B., Luxenburger, A., Lucas, N. T., Hawkins, B. C., & Hinkley, S. F. R. (2020). The synthesis of 3-azabicyclo[4.3.0]nonane scaffolds from Brefeldin A. Tetrahedron Letters, 61, 152006. doi: 10.1016/j.tetlet.2020.152006
Journal - Research Article
Hall, T. B. J., Hoggard, B. R., Larsen, C. B., & Lucas, N. T. (2019). Synthesis of cyclopenta-HBCs and their regioselective chlorination during oxidative cyclodehydrogenation. Chemistry: An Asian Journal, 14, 1106-1110. doi: 10.1002/asia.201801812
Journal - Research Other
Barnsley, J. E., Shillito, G. E., Larsen, C. B., van der Salm, H., Horvath, R., Sun, X. Z., … Lucas, N. T., & Gordon, K. C. (2019). Generation of microsecond charge-separated excited states in rhenium(I) diimine complexes: Driving force is the dominant factor in controlling lifetime. Inorganic Chemistry, 58, 9785-9795. doi: 10.1021/acs.inorgchem.9b00792
Journal - Research Article
Gai, S., Lucas, N. T., & Hawkins, B. C. (2019). Benzannulated 6,5-spiroketals from donor-acceptor cyclopropanes. Organic Letters, 21(8), 2872-2875. doi: 10.1021/acs.orglett.9b00878
Journal - Research Other
Smith, J. N., & Lucas, N. T. (2018). Rigid tetraarylene-bridged cavitands from reduced-symmetry resorcin[4]arene derivatives. Chemical Communications, 54, 4716. doi: 10.1039/c8cc01903g
Journal - Research Other
Smith, J. N., Hook, J. M., & Lucas, N. T. (2018). Superphenylphosphines: Nanographene-based ligands that control coordination geometry and drive supramolecular assembly. Journal of the American Chemical Society, 143(3), 1131-1141. doi: 10.1021/jacs.7b12251
Journal - Research Article
Barnsley, J. E., Shillito, G. E., Mapley, J. I., Larsen, C. B., Lucas, N. T., & Gordon, K. C. (2018). Walking the emission tightrope: Spectral and computational analysis of some dual-emitting benzothiadiazole donor-acceptor dyes. Journal of Physical Chemistry A, 122(40), 7991-8006. doi: 10.1021/acs.jpca.8b05361
Journal - Research Article
Lamb, R. A., Lucas, N. T., Lessene, G., & Hawkins, B. C. (2018). Strategies, setbacks, and successes in the synthesis of (-)-spiroleucettadine. Journal of Organic Chemistry, 83(17), 10120-10133. doi: 10.1021/acs.joc.8b01404
Journal - Research Article
Shillito, G. E., Hall, T. B. J., Preston, D., Traber, P., Wu, L., Reynolds, K. E. A., … Lucas, N. T., Crowley, J. D., … Gordon, K. C. (2018). Dramatic alteration of 3ILCT lifetimes using ancillary ligands in [Re(L)(CO)3(phen-TPA)]n+ complexes: An integrated spectroscopic and theoretical study. Journal of the American Chemical Society, 140(13), 4534-4542. doi: 10.1021/jacs.7b12868
Journal - Research Article
Adams, B. S., Shillito, G. E., van der Salm, H., Horvath, R., Larsen, C. B., Sun, X.-Z., Lucas, N. T., … Gordon, K. C. (2017). Alteration of intraligand donor-acceptor interactions through torsional connectivity in substituted Re-dppz complexes. Inorganic Chemistry, 56, 12967-12977. doi: 10.1021/acs.inorgchem.7b01710
Journal - Research Article
Kim, T. Y., Digal, L., Gardiner, M. G., Lucas, N. T., & Crowley, J. D. (2017). Octahedral [Pd6L8]12+ metallosupramolecular cages: Synthesis, structures and guest-encapsulation studies. Chemistry: A European Journal, 23, 15089-15097. doi: 10.1002/chem.201702518
Journal - Research Article
Lamb, R. A., Aberle, N. S., Lucas, N. T., Lessene, G., & Hawkins, B. C. (2017). Total synthesis of (—)-Spiroleucettadine [Brief communication]. Angewandte Chemie International Edition, 56(46), 14663-14666. doi: 10.1002/anie.201708110
Journal - Research Article
Elliott, A. B. S., Horvath, R., Sun, X.-Z., Gardiner, M. G., Müllen, K., Lucas, N. T., … Gordon, K. C. (2016). Long-lived charge transfer excited states in HBC-polypyridyl complex hybrids. Inorganic Chemistry, 55(10), 4710-4719. doi: 10.1021/acs.inorgchem.5b02602
Journal - Research Article
Larsen, C. B., van der Salm, H., Shillito, G. E., Lucas, N. T., & Gordon, K. C. (2016). Tuning the rainbow: Systematic modulation of donor-acceptor systems through donor substituents and solvent. Inorganic Chemistry, 55(17), 8446-8458. doi: 10.1021/acs.inorgchem.6b01039
Journal - Research Article
Rodpun, K., Lucas, N. T., Tan, E. W., & Meledandri, C. J. (2016). Development of solvent-dispersible coordination polymer nanocrystals and application as efficient heterogeneous catalysts. Crystal Growth & Design, 16(7), 3940-3946. doi: 10.1021/acs.cgd.6b00502
Journal - Research Article
Wright, J. R., Crowley, J. D., & Lucas, N. T. (2016). Carbon-rich "click" 1,2,3-triazoles: Hexaphenylbenzene and hexa-peri-hexabenzocoronene-based ligands for Suzuki-Miyaura catalysts. Chemical Communications, 52(88), 12976-12979. doi: 10.1039/c6cc07413h
Journal - Research Article
Craig, A. J., van der Salm, L., Stevens-Cullinane, L., Lucas, N. T., Tan, E. W., & Hawkins, B. C. (2015). Expedient metal-free synthesis of 1,3-oxazinen-4-ones. Organic Letters, 17(2), 234-237. doi: 10.1021/ol503350h
Journal - Research Article
Rodpun, K., Blackman, A. G., Gardiner, M. G., Tan, E. W., Meledandri, C. J., & Lucas, N. T. (2015). Alkyl linker effects on the coordination topology of ditopic di(2-pyridylmethyl)amine carboxylate ligands with ZnII and CuII: Polymers vs. macrocycles. CrystEngComm, 17(15), 2974-2988. doi: 10.1039/c5ce00375j
Journal - Research Article
Hoggard, B. R., Larsen, C. B., & Lucas, N. T. (2014). Site selectivity of [RuCp*]+ complexation in cyclopenta[def]triphenylenes. Organometallics, 33(21), 6200-6209. doi: 10.1021/om5008852
Journal - Research Article
Tomar, M., Lucas, N. T., Müllen, K., & Jacob, J. (2013). Facile synthesis and coupling of 3,9-dibromo-6-aryl-5H-dibenzo[d,f][1,3]diazepine derivatives. Tetrahedron Letters, 54(44), 5883-5885. doi: 10.1016/j.tetlet.2013.08.107
Journal - Research Article
Wright, J. R., Young, P. C., Lucas, N. T., Lee, A.-L., & Crowley, J. D. (2013). Gold(I) and Palladium(II) complexes of 1,3,4-trisubstituted 1,2,3-triazol-5-ylidene "click" carbenes: Systematic study of the electronic and steric influence on catalytic activity. Organometallics, 32(23), 7065-7076. doi: 10.1021/om400773n
Journal - Research Article
Baker, R. W., Radzey, H., Lucas, N. T., & Turner, P. (2012). Stereospecific syntheses and structures of planar chiral bidentate η5:κS-indenyl - sulfanyl and -sulfinyl complexes of rhodium(III). Organometallics, 31(15), 5622-5633. doi: 10.1021/om300581r
Journal - Research Article
Bartenstein, J. E., & Lucas, N. T. (2012). Reduced symmetry triflate-resorcin[4]arenes. Supramolecular Chemistry, 24(8), 618-626. doi: 10.1080/10610278.2012.703324
Journal - Research Article
Anant, P., Mangold, H., Lucas, N. T., Laquai, F., & Jacob, J. (2011). Synthesis and characterization of donor-acceptor type 4,4'-Bis(2,1,3-benzothiadiazole)-based copolymers. Polymer, 52(20), 4442-4450. doi: 10.1016/j.polymer.2011.07.053
Journal - Research Article
Scaria, R., Lucas, N. T., Müllen, K., & Jacob, J. (2011). Blue-emitting copolymers of isoquinoline and fluorene. Reactive & Functional Polymers, 71(8), 849-856. doi: 10.1016/j.reactfunctpolym.2011.05.006
Journal - Research Article
Anant, P., Lucas, N. T., Ball, J. M., Anthopoulos, T. D., & Jacob, J. (2010). Synthesis and characterization of pyrene-centered oligothiophenes. Synthetic Metals, 160(17-18), 1987-1993. doi: 10.1016/j.synthmet.2010.07.022
Journal - Research Article
Saini, G., Lucas, N. T., & Jacob, J. (2010). Tetrathiophenes with thiophene side chains: Effect of substitution on packing and conjugation. Tetrahedron Letters, 51, 2956-2958. doi: 10.1016/j.tetlet.2010.03.087
Journal - Research Article
Li, Z., Zhi, L., Lucas, N. T., & Wang, Z. (2009). Triangle-shaped polycyclic aromatics based on tribenzocoronene: Facile synthesis and physical properties. Tetrahedron, 65(17), 3417-3424. doi: 10.1016/j.tet.2009.02.042
Journal - Research Article
Shi, Y., Qian, H., Lucas, N. T., Xu, W., & Wang, Z. (2009). Synthesis of a three-dimensional spiro-annulated polycyclic aromatic hydrocarbon. Tetrahedron Letters, 50(28), 4110-4113.
Journal - Research Article
Anant, P., Lucas, N. T., & Jacob, J. (2008). A simple route toward the synthesis of bisbenzothiadiazole derivatives. Organic Letters, 10(24), 5533-5536. doi: 10.1021/ol8022837
Journal - Research Article
Kokkin, D. L., Troy, T. P., Nakajima, M., Nauta, K., Varberg, T. D., Metha, G. F., Lucas, N. T., & Schmidt, T. W. (2008). The optical spectrum of a large isolated polycyclic aromatic hydrocarbon: Hexa-peri-hexabenzocoronene, C42H18. Astrophysical Journal, 681, L49-L51.
Journal - Research Article
El Hamaoui, B., Zhi, L., Wu, J., Li, J., Lucas, N. T., Tomović, Ž., … Müllen, K. (2007). Solid-state pyrolysis of polyphenylene-metal complexes: A facile approach toward carbon nanoparticles. Advanced Functional Materials, 17, 1179-1187. doi: 10.1002/adfm.200600826
Journal - Research Article
Lucas, N. T., Zareie, H. M., & McDonagh, A. M. (2007). Self-organization of a discotic coordination complex bearing orthogonal discotic ligands. ACS Nano, 1(4), 348-354. doi: 10.1021/nn700187b
Journal - Research Article
Cifuentes, M. P., Powell, C. E., Morrall, J. P., McDonagh, A. M., Lucas, N. T., Humphrey, M. G., … Isoshima, T. (2006). Electrochemical, spectroelectrochemical, and molecular quadratic and cubic nonlinear optical properties of alkynylruthenium dendrimers. Journal of the American Chemical Society, 128(33), 10819-10832. doi: 10.1021/ja062246v
Journal - Research Article